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    26th Annual Indonesian Geologist AssociationJoin Convention Bali, 2007

    Full Paper Submission

    Corresponding Author: Dasapta Erwin Irawan

    Address:Research Division on Applied GeologyFaculty of Earth Science and TechnologyInstitut Teknologi BandungBasic Science building 3

    thfloor

    Jl. Ganesa no 10, Bandung - 40132

    Email:[email protected],Tel/Fax: 022-251 0802

    Title of paper:Outlining Hydrogeological System using Multivariate Analysis on Groundwater Quality at Mt.Ciremai, West Java, Indonesia

    Author(s) and Affiliations1. D. Erwin Irawan2. Deny Juanda PuradimajaResearch Group on Applied Geology, Faculty of Earth Sciences and Technology,Institut Teknologi Bandung, Jl. Ganesha No. 10, 40132 Bandung, Indonesia (e-mail: [email protected])3. Sudarto NotosiswoyoResearch Group on Earth Resources Exploration, Faculty of Mining and Petroleum Engineering,Institut Teknologi Bandung, Jl. Ganesha No. 10, 40132 Bandung, Indonesia (e-mail:[email protected])

    Abstract (no more than 200 words)

    Volcanic slopes are important sources of water. Groundwater observation in east slope of Ciremai wasconducted in period of dry season of May until June 2006 on 119 springs. Fourteen variables wasmeasured: elevation, spring discharge, TDS, EC, pH, T water, T air, calcium, magnesium, chloride,sodium, sulphate, potassium, bicarbonate.

    Cluster analysis has successfully extracted 3 clusters: cluster 1 (112 obs), cluster 2 (5 obs), cluster 3(2 obs). The hydrogeological schematization has been constructed based on interpretations of 3clusters. There are 3 hydrogeological systems: 1) Hydrogeological system 1 is characterized by:cluster 1, heterogeneous data, normal water temperature, TDS, EC, and major elementsconcentrations, and many chemical influences. 2) Hydrogeological system 2 is characterized by:cluster 2, homogeneous data, high water temperature, TDS, EC, the result of interaction betweennormal meteoric water and hot water of volcanic origin. 3) Hydrogeological system 3 is characterizedby: cluster 3, high water temperature, TDS, and EC with homogeneous characters, deep flow system,

    and interaction with sedimentary layers of Fm. Kaliwungu.

    Key words:1 Stratovolcanoes2 HydrogeologicalTracer3 Multivariate analysis

    mailto:[email protected]:[email protected]:[email protected]:[email protected]
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    Outlining Hydrogeological System using Multivariate Analysis on Groundwater Quality

    at Mt. Ciremai, West Java, Indonesia

    D. Erwin Irawan1, Deny Juanda Puradimaja1, Sudarto Notosiswoyo2

    1Research Group on Applied Geology, Faculty of Earth Sciences and Technology,

    Institut Teknologi Bandung, Jl. Ganesha No. 10, 40132 Bandung, Indonesia (e-mail: [email protected])

    2Research Group on Earth Resources Exploration, Faculty of Mining and Petroleum Engineering, Institut

    Teknologi Bandung, Jl. Ganesha No. 10, 40132 Bandung, Indonesia (e-mail: [email protected])

    Abstract

    Volcanic slopes are important sources of water. Groundwater observation in east slope of

    Ciremai was conducted in period of dry season of May until June 2006 on 119 springs.

    Fourteen variables was measured: elevation, spring discharge, TDS, EC, pH, T water, T air,

    calcium, magnesium, chloride, sodium, sulphate, potassium, bicarbonate.

    Cluster analysis has successfully extracted 3 clusters: cluster 1 (112 obs), cluster 2 (5 obs),cluster 3 (2 obs). The hydrogeological schematization has been constructed based on

    interpretations of 3 clusters. There are 3 hydrogeological systems: 1) Hydrogeological system

    1 is characterized by: cluster 1, heterogeneous data, normal water temperature, TDS, EC, and

    major elements concentrations, and many chemical influences. 2) Hydrogeological system 2

    is characterized by: cluster 2, homogeneous data, high water temperature, TDS, EC, the result

    of interaction between normal meteoric water and hot water of volcanic origin. 3)

    Hydrogeological system 3 is characterized by: cluster 3, high water temperature, TDS, and

    EC with homogeneous characters, deep flow system, and interaction with sedimentary layers

    of Fm. Kaliwungu.

    1. Introduction

    Indonesia is a part of ring of fire, consisting of almost 128 volcanoes. In other figure, 13

    17% of worlds volcanoes are located in Indonesia. Such large number of volcanoes makes

    Indonesia one of important country to solve volcanoes problems. Subduction zone lies across

    the country forming volcanic belt, most of it are strato volcano. Hundreds of volcanoes

    produce volcanic deposit which covers 33,000 km2or one sixth of Indonesias land (Dept. of

    Mining and Energy, 1979).

    At this volcano, volcanic deposit plays role as productive aquifer, as shown by the emergence

    of spring belt with enormous discharge and excellent quality. The aquifer comes as porous

    system as well as fracture system. For an example on Mt. Ciremai, there are at least 116

    springs with variable discharge, from 10 liter/seconds to 1000 liter/seconds.

    This paper describes the hydrological assessment performed on the Mt. Ciremai (Figure 1).

    Here we analysed 116 springs around the volcano on water quality and quantity. The results

    show radial flow patterns, a dependency on slope aspect and altitude and lithology. This paper

    will elaborate on the relationship between volcanic geomorphology and hydrology that was

    found and discuss how this information could be used for assessing the spatial patterns of

    local groundwater systems on volcanic slopes. Lastly, we make a spatial water balance to

    illustrate the regional differences in water availability.

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    2. Problem Statement

    On the Java island Indonesia, the water demand increases due to population growth and rising

    water consumption per capita (Puradimaja et.al, 2004). Although Indonesian islands receive

    abundant precipitation (2000 - 4000 mm/yr), it is not well distributed both spatially and

    temporarily. For example the Java Island shows large spatial differences of rainfall betweenthe coastal areas (less than 250 mm/yr) and volcanic areas (more than 2500 mm/yr). The

    monsoon climate divides the year in a clear dry and wet period.

    Water scarcity, especially for agriculture is a well-known problem in Indonesia. However, the

    water resources are not managed yet in this respect. By example, upslope movement of

    habitation and agriculture changes the water budget of that particular region and influences

    the amount of stream water available downstream.

    3. Literature Review

    3.1 Hydrogeological SettingMount Ciremai is a solitaire-strato volcano with elevation of 3072 masl, situated at

    Majalengka (west flank) and Kuningan Regency (East flank) (Figure 2), 20 km south of

    Cirebon, Indonesia. It lies at 6 53 30 latitude and 10824 00 longitude. The diameter of

    this volcano, from the peak to the foot slope is about 10 km. Mt. Ciremai has recorded 5

    eruptions in 1698, 1772, 1775, 1805, and 1937, with 3 -112 years interval, historically. Those

    eruptions produced 22 volcanic deposits, consist of: 11 lava flows, 9 pyroclastic materials,

    and 2 laharic breccias. Many studies have been conducted in the area.

    Situmorang (1995) has published the volcanic geological map of Mt. Ciremai. According to

    the author, the exposed volcanic deposit was produced by 4 generation of eruptions, which

    generated 3 types of deposits. Lava flow consists of andesite rock, black to brownish incolour. It has fractures, cooling joints and columnar joints due to mass unloading and cooling

    processes. Pyroclastic materials consist of andesite fragments planted in tuff lithic and tuff

    crystal. It comes in flowing and falling mechanisms. Laharic breccias consist of andesite

    fragments planted in volcanic sands, tuff lithic, and tuff crystal. It comes in water dominant

    flowing mechanisms. The first regional hydrogeology condition was introduced by IWACO

    WASECO (1989). Regional aquifer system at Mt. Ciremai area is divided in to 3 systems:

    Surficial Alluvium, Quaternary Volcanic (Young Volcanic), and Tertiary Sediment system.

    More details study was conducted by Puradimaja et.al (2003). According to the author, there

    are 3 main aquifer units: pyroclastic breccias, lava, and laharic breccias. All of the observed-

    aquifers are unconfined aquifers. The aquifer feeds water to spring zone encircling Mt.

    Ciremai. The spring zone is interpreted to be following slope morphology which controlled by

    change of rock distribution. Such condition forms 2 slope breaks at 750 masl (4o difference)

    and 1350 masl (19o difference).

    Irawan (2006) stated that there 3 factors which control the spring emergence. First factor is

    the change of rock distribution from lava to laharic breccias. Morphological features in form

    of ridges and valleys also contribute to control groundwater flow pattern. Second factor is

    fracture and continuous voids zone controls the level of spring discharge in volcanic terrain.

    Third factor is the weathering processes in the study area is very intensive, resulting in thick

    residual soil and high final infiltration rate, which is very potential to store and to be

    infiltrated by rain water and surface water.There were 3 thermal groups of spring, based on 23 spring observations, consists of:

    hypothermic, mesothermic, and hyperthermic (Figure 3). Based on the thermal classification,

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    it can be interpreted that thermal differences were triggered by interaction between

    groundwater temperature and environmental temperature. The hypothermic group shows the

    closed system of groundwater. Mesothermic group shows the interaction between

    groundwater and surface temperature. Hyperthermic groups were characterized by the

    interaction of groundwater with specific subsurface heat source. (Hem, 1970 and Matthess,

    1982). Piper plot is presented in Figure 4, to show the differentiation of chemical characters.

    The intensity of weathering processes in the study area is very high, indicated by 2 m tonearly 10 m of soil thickness. Such thick residual soil is very potential to store and to infiltrate

    rain and surface water in to the aquifer. Infiltration tests (according to Chow et.al. 1964;

    Miyazaki, 1993) was carried out to verify the final infiltration rate of residual soils. Residual

    soil from lahars shows the largest values of 1.26 2.53 cm/min, followed by residual soil

    from pyroclastic breccias 1.5 cm/min, and from lava flow 0.5 1.2 cm/min. High final

    infiltration rate (Linsley & Franzini, 1978) indicates the high capacity of residual soil to be

    infiltrated by rain water and surface water.

    Subsequently, in 2002, Bapeda Kuningan Regency has mapped 161 springs with total of

    8285.2 l/sec. The result is five classes of spring discharge magnitude (Meinzer 1923, op.cit

    Todd, 1980): Six springs of Class II (4%), 44 springs of Class III (27%), 15 springs of ClassIV (9%), 40 springs of Class V (25%), 56 springs of Class VI (35%). Both preceding studies

    have not analysed the control of geological setting to groundwater springs.

    3.2 Cluster Analysis

    Cluster analysis is an unsupervised-multivariate statistical method that identifies the

    hierarchial structure of similarity of large number observations in to into groups. Thus, that

    the objects within a group are very similar and objects from different groups are significantly

    different in their characteristics (Smith, 2002). There are 3 steps in cluster analysis (McGraw-

    Hill, 2007)

    Step 1: Select cluster variables and distance measures. How many and which variables are to

    be selected will affect the analysis results. In cluster analysis, it is implicitly assumed

    that every variable is equally important.

    Step 2: Select cluster algorithm. Cluster algorithm is the procedure to determine clusters,

    or groups. There are two categories of cluster algorithms, hierarchical and non-

    hierarchical. In this paper, we are going to use hierarchical algorithms.

    Step 3: Perform cluster analysis. Cluster analysis will determine the cluster structure

    specifically, which objects form a cluster, how many clusters, the features of clusters,

    etc.

    Step 4: Interpretation. We need to explain what these clusters mean and how should wename and make sense of these clusters. The interpretation is based on geological

    facts.

    According to McGraw-Hill (2007), in cluster analysis, distance is used to represent how

    close each pair of objects is. The most common distance measurement is Euclidean Distance

    (Figure 6). The Euclidean distance between any two objects, that is, the distance between

    object i and object k(dik), is

    N

    j

    kjijik xxd

    1

    2)( Equation 1

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    In cluster analysis, it is desirable that the distances between objects within a cluster (group)

    are small and the distances between different clusters are large, as illustrated in Figure 6. The

    definition of the distance between clusters depends on the methods to determined relationship

    between clusters, called linkage. There are several different linkage methods which we will

    discuss as follows. In single linkage method, the distance between two clusters is defined to

    be the distance of the nearest neighbours (Figure 6). Specifically, assume that we have two

    clusters, clusterR and cluster S. Let rrepresent any element in cluster R, and let s representany element in cluster S. Then the distance between cluster R and cluster S in single linkage

    method is defined as

    SsRrdd rsSR ,min))(( Equation 2

    In a dendogram, the distances between clusters and the joining process are described very

    well. We usually want to form more than a cluster in further analysis. As we discussed earlier,

    a good clustering should be as follows:

    1. The objects within a cluster should be similar one another, in other words, the distances

    between the objects within a cluster should be small.

    2. The objects from different clusters should be dissimilar, significantly, or the distancesbetween them should be large.

    4. Methodology

    The delineation of groundwater systems aims: 1). the recognition of the hydrogeological

    boundaries enclosing the system; 2) the mechanisms of recharge, and discharge, along with

    the flow paths of groundwater from recharge areas to discharge areas Mandel & Shiftan

    (1981). In order to map the hydrogeological boundaries and rechargedischarge mechanism,

    this research used 3 main approaches: desk study, hydrogeological mapping, hydrochemical

    sampling and analysis. Detailed work describes as follows.

    1) Desk study: The desk study consisted of studying the topographical map, geological maps,

    hydrogeological maps, and re-analyses of previous studies;

    2) Hydrogeological mapping: The hydrogeological mapping is based spring observations;

    consist of: coordinates, local geological observations, measurement of the spring

    discharges and the water qualities. The discharge was measured using the area-velocity

    method. The water velocity was measured using current meter. For small discharge (less

    then 1 l/s), the measurements were taken using volumetric method with a 10 liter bucket

    and stopwatch. Duplets measurements were taken at each observation.

    3) Hydrochemical sampling: At each location, physical parameters measurements were takenconsist of: air temperature, water temperature, Electro-Conductivity (EC), Total Dissolved

    Solids (TDS), and pH. The air temperature was measured only during sampling using a

    standard thermometer, while other above parameters were measured using Lutron portable

    equipment. For laboratory chemical analysis, the spring water was sampled using 1 litre

    plastic bottles. The duplets laboratory analysis comprises: the calculation of major

    elements concentrations using titration method. Chemical test results have to be validated

    using ion balance equation (see equation 3), before further analyses. We determined 20%

    error balances as permit-able limit. Samples have higher than 20% of error balance will be

    re-tested while samples have lower than 20% error will be analyzed.

    [( cations - anions) / ( cations + anions)] x 100% equation 3

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    4) Statistical analysis: The hydrochemical parameters and the result from field observations

    were analyzed using basic statistical analysis and cluster analysis to assist the

    hydrogeological analysis, by using Minitab (trial version).

    5) Interpretation: The interpretation aims to schematization of hydrogeological system based

    on each spring clustering.

    5. Analysis and Interpretations

    The survey was conducted in period of May until June 2006, in dry season. As much as 119

    springs from east slope. At each spring, there were 14 variables measurements (see Table 3):

    Elevation (Elev) in masl, Discharge (Q) in liter/sec, Total Dissolved Solids (TDS) in ppm,

    Electro Conductivity (EC) in micro Siemens/cm, Acidity (pH), Water temperature (W.temp)

    (oC), Air temperature (A. temp) in oC, Major elements concentration (mg/l): calcium (Ca2+

    ),

    magnesium (Mg2+

    ), chloride (Cl-), sodium (Na

    +), sulfate (SO4

    2-), potassium (K

    +), bicarbonate

    (HCO3-).

    Large deviations as shown by several variables: TDS, EC, hardness, chloride, sodium, andbicarbonate. This should affect to the clusters. Observations with maximum value of those

    variables should separate relatively from the other observations with normal value. In this

    section, we are going to discuss the spring clustering and dominant variables which control

    the springs.

    5.1 Cluster Analysis

    Cluster analysis, with Minitab (trial version) has successfully extracted 3 clusters. Cluster 1

    consists of 112 observations, cluster 2 comprises 5 observations, cluster 3 consists of 2

    observations (see table 4 and figure 7). Cluster 1 shows more variation as shown by the large

    maximum distance from centroid (9.23), relatively to cluster 2 (3.05).

    5.2 Outlining Hydrogeological Systems

    The outline of hydrogeological system is based on schematization of 3 clusters. The

    interpretations lead to 3 hydrogeological systems (Figure 8): Hgl 1, Hgl 2, and Hgl 3.

    Hydrogeological system 1 (Hgl 1 112 obs) is characterized by large variations of data with

    normal values of water temperature, TDS, EC, and major elements concentrations. This

    condition is due to the many chemical influences as the groundwater flow from recharge area

    to discharge area in unconfined aquifer system of 3 lithological type (from up to down):

    pyroclastic breccias, lava, and laharic breccias.Hydrogeological system 2 (Hgl 2 5 obs) is described as more homogeneous observations

    with anomalous values: high water temperature, TDS, and EC. The groundwater is interpreted

    as the result of interaction between normal meteoric water and hot water of volcanic origin.

    Hydrogeological system 3 (Hgl 3 2 obs) is separated by other 2 clusters due to the

    homogeneous characters (spring number 65 and 100) with deeper flow system, compared to

    Hgl 2. The 2 springs, Cikalamayan (65) and Liang Panas (100), have high concentrations of

    chloride along with high water temperature. Major elements concentration is interpreted to

    be the effect of interaction between hot water with sedimentary layers of Fm. Kaliwungu,

    which deposited in sea environment. Layers of sand and clay in the formation below

    Ciremais volcanic deposits, contribute to the high chloride content in the groundwatersamples.

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    6. Conclusions

    Cluster analysis has successfully extracted 3 clusters: cluster 1 (112 obs), cluster 2 (5 obs),

    cluster 3 (2 obs). The hydrogeological schematization has been constructed based on

    interpretations of 3 clusters. There are 3 hydrogeological systems: 1) Hydrogeological system

    1 (Hgl 1112 obs) is characterized by: heterogeneous data, normal water temperature, TDS,

    EC, and major elements concentrations. This condition is due to the many chemical

    influences as the groundwater flow from recharge area to discharge area in unconfined aquifersystem. 2) Hydrogeological system 2 (Hgl 2 5 obs) is characterized by: homogeneous data,

    high water temperature, TDS, EC. The groundwater is interpreted as the result of interaction

    between normal meteoric water and hot water of volcanic origin. 3) Hydrogeological system 3

    (Hgl 3 2 obs) is characterized by: homogeneous characters with deeper flow system. High

    concentrations of chloride along with high water temperature are interpreted to be the effect

    of interaction between hot water with sedimentary layers of Fm. Kaliwungu, which deposited

    in sea environment.

    Acknowledgement

    The authors would like to thank The Board for Regional Planning Kab. Kuningan for

    facilitating data and Director of PDAM Kab. Kuningan for access to spring abstraction site.

    We also would like to thank our team of undergraduate students that gave their time and effort

    to help us surveying spring data and gathering the first level analysis.

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    References

    Bapeda Kuningan, 2002, Inventarisasi Mataair Kab. Kuningan, Bapeda Kuningan.

    Chow, 1964, Soil Water, Prentice-Hall.

    Costello, A.B. and Osborne, J.W., 2005, Best Practices in Exploratory Factor Analysis: FourRecommendations for Getting the Most From Your Analysis, Practical

    Assessment Research & Evaluation, Vol 10, No 7.

    Dept. Pertambangan dan Energi, 1979, Data Dasar Gunungapi Indonesia, Dept. Pertambangan

    dan Energi.

    Hem. J.D., 1973, Study and Interpretation of Natural Water, USGS Water Supply Paper.

    Irawan, D.E. and Puradimaja, D.J., 2006, The Differentiation of Hyperthermal Groundwater

    Origin by using Multivariate Statistics on Water Chemistry, Journal Geoaplika,

    vol 1, no 2.

    Irawan, D.E.and Puradimaja, D.J., 2006, The Hydrogeology of The Volcanic Spring Belt,East Slope of Gunung Ciremai, West Java, Indonesia, Proceeding of IAEG

    Conference.

    IWACO WASECO, 1989, Kuningan Regency Provincial Water Supply Report, Dept. of

    Public Works.

    Kitano, Y. (ed), 1975, Geochemistry of Water, Benchmark Paper in Geology, Hutchinson &

    Ross, Pennsylvania, pp. 273296.

    Linsley, R.K., Franzini, J.B., Freyberg, D.L., Tchobanoglus, G., 1992, Water resources

    engineering, McGraw-Hill, New York.

    Mandel and Shiftan, 1981, Groundwater resources: Investigation and Development,

    Academic Press.

    Matthess, G., 1982, Properties of Groundwater, McGraw-Hill.

    Miyazaki, T., 1993, Groundwater Basin Management, Tokai University Press

    Multivariate Statistical Methods and Quality, Downloaded from Digital Engineering Library

    @ McGraw-Hill (www.digitalengineeringlibrary.com), McGraw-Hill.

    Puradimaja, D.E., Sukarno, I., Abidin, Z., Irawan, D.E., 2002, Sistem Pengembangan dan

    Pengusahaan Air Bersih di Jawa Barat. Potensi dan Pola Bisnis Air Bersih serta

    Air Minum, Dipresentasikan pada acara Seminar Pemanfaatan dan Pengelolaan

    Air Bersih Guna Meningkatkan Kesehatan Masyarakat Jawa Barat Menuju Era

    Globalisasi, Aula Barat ITB, 22 Nopember 2002.

    Puradimaja, D.J, Irawan, D.E., Hutasoit, L.M., 2003, The Influence of Hydrogeological

    Factors on Variations of Volcanic Spring Distribution, Spring Discharge, and

    Groundwater Flow Pattern, Bulletin of Geology, Vol 35, No 1/2003, pp: 1523,

    ISSN: 0126-3498.

    Situmorang, 1995, Peta Geologi Gunung Ciremai, Direktorat Vulkanologi.

    Smith, L.I., 2002, A Tutorial on Cluster Analysis, downloaded from

    http://www.cs.montana.edu.

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    Figures and tables

    Figure 1 The location map of Mt. Ciremai. Box marks the study area. The area is moreless20 km south from Cirebon, West Java.

    Scale 1 :

    Locati

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    Figure 3 Chart of thermal gradient of groundwater at Ciremai (Puradimaja, D.J., et.al. 2003).

    Figure 4 Piper plots of chemical composition (Puradimaja, et.al, 2003).

    K L A S I F I K A S I T E R M A L M A T A A I R

    y = 4 0 9 3 . 4 0 9 - 1 5 2 . 6 9 9 * x

    T A

    E

    1 12 1

    3 24 3

    5 3

    6 37 38 39 3

    1 2 3

    1 4 3

    1 5 3 1 6 31 7 3

    1 8 3 1 9 32 0 3

    2 1 12 2 1

    1 0 2 1 1 2

    2 3 32 4 3

    2 5 3

    2 0 0

    4 0 0

    6 0 0

    8 0 0

    1 0 0 0

    1 2 0 0

    1 4 0 0

    k e lo m p o k m e s o t e r m a l

    k e lo m p o k h i p o t e r m a l k e lo m p o k h i p e r t e r m a l

    k e lo m p o k h i p e r t e r m a lTransition zone

    Elevation

    (masl)

    Water Temperature (oC)

    R2=0,81

    Mg

    Ca

    100

    0

    0

    100

    Cl

    SO4

    0

    100

    100

    0

    SO

    +C

    l

    4

    Ca+Mg

    Na+K

    100

    100

    0

    100

    0

    CO

    +

    HCO

    3

    3

    100

    0

    0

    2

    4

    67

    89

    2

    4

    4

    6

    6

    7

    7

    8

    8

    9

    9

    1

    1

    2

    1

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    GEOLOGICALMAP

    HYDROGEOLOGICALMAP

    HYDROGEOLOGICALSURVEY

    SPRINGOBSERVATION

    PHYSICO-CHEMICAL

    MEASUREMENTS

    CLUSTERANALYSIS

    INTERPRETATION

    Table 1 Characteristics of various multivariate analyses

    Method Interdependencevs. dependence

    Exploratory vs.confirmatory

    Metric vs.non metric

    Objectives

    Principal ComponentAnalysis

    interdependence Exploratory Metric Dimension reduction

    Exploratory Factor

    Analysis

    interdependence Confirmatory Metric Understand correlation

    patterns, uncover latent

    traits

    Multidimensional

    Scaling

    interdependence Exploratory Metric or non

    metric

    Verify measurement

    model

    Cluster Analysis interdependence Exploratory Metric or non

    metric

    Create spatial

    representation from

    object similarities

    Canonical Correlation dependence Exploratory Metric Explain covariationbetween 2 sets multiple

    variables

    Analysis of Variance dependence Confirmatory Metric andnon metric

    Special case ofcanonical correlation

    with discrete X

    variables.

    Discriminant

    Analysis

    dependence Exploratory or

    confirmatory

    Metric and

    non metric

    Special case of

    canonical correlation

    with discrete Y

    variables.

    Figure 5 The work flow of the research

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    Table 2 Laboratorymethods for major element measurements

    No Parameters Units Methods

    1 Hardness (CaCO3) mg/l SMEWW 2340-C

    2 Calcium (Ca2+) mg/l SMEWW 3500-Ca

    3 Magnesium (Mg2+) mg/l SMEWW 3500-Mg

    4 Chloride (Cl-) mg/l SMEWW 4500-Cl

    5 Sodium (Na+) mg/l SMEWW 4500-Na

    6 Sulphate (SO42-) mg/l SMEWW4500-SO4

    7 Potassium (K+) mg/l SMEWW 3500-K

    8 Bicarbonate (HCO3-) mg/l SNI 06-2420

    Figure 6 Illustration of what is Euclidean distance (upper left), cluster distance and between

    cluster distance (upper right), and dendogram as the final results of cluster analysis (lower).

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    Table 3 Descriptive analysis of the variables. Large deviations as shown by several variables:

    TDS, EC, hardness, chloride, sodium, and bicarbonate should affect the clustering processes.

    Observations with maximum value of those variables should separated relatively from the

    other observations with normal value.

    Variable Mean StDev Minimum Maximum

    Elevation (Masl) 491.6 237 111 1273

    Discharge (Q) (l/s) 17.522 8.6 1.3 40.3

    TDS (ppm) 159.6 221.7 16 1001

    EC (mS/cm) 130.3 102.8 16.3 515.5

    pH 7.221 0.6 6.2 9

    W.temp 25.635 4.4 18.4 61.4

    A.temp 28.581 3.1 21.5 42

    Hardness (CaCO3) 144.4 331.7 28.2 2488.8

    Calcium (Ca2+

    ) 26.07 39.5 8 283.4

    Magnesium (Mg2+

    ) 21.87 61.5 1.4 432

    Chloride (Cl-) 564 2536 2 13100

    Sodium (Na+) 426 1916 5 10000

    Sulfate (SO42-

    ) 14.34 23 0 120

    Potassium (K+) 13.96 41 2 210

    Bicarbonate (HCO3-) 181.9 409.5 12 2098.4

    Table 4 Cluster analysis results (Minitab trial version). Centroid is the focal point of cluster.

    Maximum distance of observation from centroid is measured on each cluster. Cluster 1 shows

    more variation as shown by the large maximum distance from centroid (9.23), relatively to

    cluster 2 (3.05).

    Average Maximum

    distance distance

    Cluster basics description Number of from from

    observations centroid centroid

    Cluster1 112 1.99 9.23Cluster2 5 1.55 3.05

    Cluster3 2 0 0

    Centroid distance

    Cluster1 Cluster2 Cluster3

    Cluster1 0 13.97 15.68

    Cluster2 13.97 0 9.28

    Cluster3 15.68 9.28 0

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    V48

    V29

    V86

    V84

    V85

    V56

    V65

    V106

    V108

    V9

    V76

    V67

    V38

    V105

    V94

    V77

    V101

    V107

    V104

    V54

    V98

    V128

    V62

    V134

    V130

    V93

    V10

    V21

    V5

    V87

    V111

    V57

    V11

    V26

    V19

    V39

    V37

    V88

    V40

    V68

    V70

    V64

    V71

    V74

    V52

    V109

    V31

    Cluster 1 (continuation)

    (112 obs)

    Cluster 2

    (5 obs)

    Cluster 3

    (2 obs)

    V100

    V14

    V59

    V81

    V96

    V73

    V95

    V35

    V13

    V34

    V92

    V53

    V15

    V55

    V102

    V131

    V91

    V97

    V17

    V6

    V18

    V4

    V72

    V99

    V69

    V90

    V51

    V103

    V80

    V60

    V27

    V20

    V3

    V46

    V28

    V133

    V79

    V132

    V110

    V22

    V112

    V129

    V61

    V89

    V58

    V36

    V47

    V7

    V44

    V66

    V83

    V30

    V82

    V41

    V78

    V75

    V45

    V32

    V25

    V63

    V33

    V24

    V2

    V1

    V42

    V12

    V23

    V50

    V8

    V43

    V49

    V16

    26,38

    50,92

    75,46

    100,00

    Observations

    Similarity

    Cluster 1 (continuation)

    (112 obs)

    Figure 7 Dendogram of cluster analysis (Minitab trial version). The lower dendogram is the

    continuation of the upper dendogram. There are 3 clusters: cluster 1 (112 observations. cluster

    2 (5 observations). and cluster 3 (2 observations).

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    0

    500

    1000

    1500

    2000

    2500

    3000

    3500

    108.15 108.2 108.25 108.3 108.35 108.4 108.45 108.5 108.55 108.6 108.65

    Elevasi

    Hgl 1

    Normal waterdescent

    Tertiary sedim ents

    0

    500

    1000

    1500

    2000

    2500

    3000

    3500

    108.15 108.2 108.25 108.3 108.35 108.4 108.45 108.5 108.55 108.6 108.65

    Elevasi

    Hgl 2Hot water rising

    Normal waterdescent

    Tertiary sedim ents

    Figure 8 The schematization of 3 hydrogeological systems. The schematization is based on

    interpretations of 3 clusters, lead to 3 hydrogeological systems: Hgl 1, Hgl 2, and Hgl 3. Hgl 1

    is volcanic-meteoric type groundwater, Hgl 2 is volcanic-transition type groundwater, Hgl 3 issedimentary-formation type groundwater.

    0

    500

    1000

    1500

    2000

    2500

    3000

    3500

    108.15 108.2 108.25 108.3 108.35 108.4 108.45 108.5 108.55 108.6 108.65

    Elevasi

    Normal waterdescent

    Hgl 3Tertiary sediments