spo terpapar bahan kimia

8/19/2019 Spo Terpapar Bahan Kimia

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Bahan bahan kimia :

1. Asam dan cairan korosif

2. Chromic dan asam Sulfat

3. Perchloric Acid

4. Hydrofluoric Acid

. Sodium !erocsida

". Bromine

#. Ammonium hydro$cide

%. Hydro&en Sul!hid

'. Cyanide( arsenic dan )ercury salt

1*. )ercury

11. +r&anic Sol,ents

12. -thers13. +r&anic halo&en com!ounds

Bahaya terhada! kesehatan

1. nhalation

/ 0in&kat ke!arahan ter&antun& dari le,el konsentrasi at yan& dihiru!.

/ a!at menyebabkan !erdarahan &usi dah hidun&

/ rritasi hidun&( mata( ten&&orokan( !aru !aru( broncho!neumonia dan oedem

!enumonia

/ Pusin&( mual( muntah( sesak na!as( tidak sadar dan &elisah

/ Akumulasi dari hydrofluoric acid dalam !aru !aru da!at saa teradi dan menyebabkan

kematian

/ 0erlalu banyak ter!a!ar den&an 0oluene( methyl benene 5C"HCH36 dan menyebabkan

kematian

2. 7ontak mata

/ a!at menyebabkan terbakar dan hilan&nya !en&elihatan. Pertolon&an !ertama san&at

!entin&

/ Hydro&en fluoride ,a!ours da!at larut !ada la!isan mata yan& lembab dan da!at

menyebabkan iritasi. Percikan ke mata da!at menyebabkan kerusakan !arah !ada

ba&ian kornea.

/

3. 0er!a!ar Asam Sulfat meski!un dalam umlah yan& sedikit da!at menyebabkan kerusakan

dan

.

Contact e,en 8ith small amounts of concentrated sul!huric acid can cause dama&e and

!ossible loss of si&ht. Contact 8ith more dilute forms of sul!huric acid can also cause

dama&e but 8ith !ossible reco,ery of si&ht. 9iuid acetone and hi&h concentrations of its ,a!our can cause moderate eye irritation.

;a!our can irritate the eyes. 9iuid can cause se,ere irritation and corrosi,e dama&e to eyesurface.



3.1.3 SKIN CONTACT Hydro&en fluoride can cause dee! and e$cruciatin&ly !ainful skin burns. Burns from stron&

H< 5*/#*=6 are felt strai&ht a8ay. >eaker solutions 52=6 may take a fe8 minutes to benoticed( solutions of 1/2*= may not be felt for se,eral hours. Serious skin s!lashes ha,ecaused death.

Concentrated acid can cause se,ere burns if not rinsed off immediately. Skin contact 8ith Pyridine causin& reddenin&( thickenin& and crackin&. Pyridine absorbed in

the skin mi&ht cause se,ere skin eru!tions in areas e$!osed to sunli&ht. Chronic skin contact to KEROSENE, PETROLEUM H YDROCARBON DISTILLATE leads to dermatitis.

Prolon&ed e$!osure has caused cases of a!lastic anaemia and death.

3.1.4 INGESTION Hydrofluoric Acid may cause se,ere burnin& and?or !erforation of the di&esti,e system may

lead to death. Hydrochloric acid causes se,ere burns of the mouth( oeso!ha&us and stomach 8ith

conseuent !ain( nausea and ,omitin&( thirst( diarrhoea( circulatory colla!se and !ossibly

death.

ACETIC ACID, GLACIAL ACETIC ACID, ETHANOIC ACID (CH3COOH) )A@ CAS- rritation of &astrointestinal tract( 8hich can result in kidney dama&e.

0oluene( )ethylBenen can cause nausea( ,omitin&( diarrhoea and loss of consciousness.

so!ro!yl Alcohol may cause dro8siness( &astro intestinal !ain( nausea( ,omitin& and

diarrhoea. 9ethal dose for humans is estimated to be a!!ro$imately 131 &.

3.2 PERSONAL PROTECTIVE EQUIPMENT

CONDITIONS INDICATIONS

SkinProtection

1. >ear !rotecti,e clothin&( includin& boots or safety shoes 8ith Poly,inyl

Chloride 5P;C6 or neo!rene.2. se chemical &o&&les and?or a full/face shield.3. >ear co,eralls 8ith lon& slee,es( &auntlets and &lo,es of P;C or

neo!rene.4. se !rotection suitable for conditions.

Eye Protection 1. se chemical safety &o&&les and?or full face shield 8here s!lashin& is!ossible.

2. )aintain eye 8ash fountain and uick drench facilities in 8ork area.

Personal Respirators(NIOSH Approved)

<or emer&encies or instances 8here the e$!osure le,els are not kno8n( use

a full/face !iece !ositi,e/!ressure( air/su!!lied es!irator.f the e$!osure limit is e$ceeded( a full/face !iece res!irator 8ith an acid

&as cartrid&e.se !rotection suitable for conditions

3.3 PROCEDURES PROTOCOL

En!"# $%# &'n#" *+#'" -" $%# %#'+$%*'"# -"/#" 'n& 0*$.U# $%# '"-"'$# P#"-n'+ P"-$#*$0# E!#n$ '#+.I&#n$ $%# *%#*'+ !5$'n*# -5+#.A# $%# '$#n$6 *-n&$-n.

3.3.1 INHALATION



Check for ABC 5an&er( es!onse( Air8ay( Circulation6

Place the ,ictim in areas 8here there is adeuate ,entilation.

Administer o$y&en 8ith hi&h concentration

Assess !atients res!onse to the o$y&en thera!y by assessin& his colour( ca!illary refill( use

of accessory muscles and res!iratory rate and ,olume.

3.3.2 EYE CONTACT <lush thorou&hly 8ith flo8in& 8ater for at least 2* minutes( holdin& eyelids a!art.

SKIN CONTACT emo,e clothin&( shoes and leather &oods from affected area.

mmediately flush area 8ith runnin& 8ater for at least 2* minutes under runnin& 8ater or other

sterile liuid. 0reat the affected skin as burn if indicated.

f the skin contact 8ith Hydrofluoric Acid( co,er affected area 8ith Calcium Dluconate &el or a

!aste of ma&nesium o$ide in the absence of Calcium Dluconate.

3.3.3 INGESTION o not induce ,omitin&

f ,ictim ,omits naturally( ha,e ,ictim lean for8ard to reduce risk of chokin&.

inse mouth 8ith 8ater.

f the ,ictim can s8allo8( &i,e one &lass 5"/% os6 of 8ater or milk to dilute material in the

stomach.

nless unconscious or con,ulsin&( induce ,omitin& by ha,in& the ,ictim drink lar&e ,olumes

of 8ater for the ,ictim 8ith so!ro!yl Alcohol.

3.4 7IRST AID MEASURES 7OR HYDRO7LUORIC ACID POISONING

3.4.1 nhalation

se the a!!ro!riate Personal Protecti,e -ui!ment safely.Use a full-face piece positive-pressure Air-supplied Respirator!

Place the ,ictim in areas 8here there is adeuate ,entilation.

Check for ABC 5an&er( es!onse( Air8ay( Breathin&( Circulation6

f breathin& has sto!!ed( be&in artificial res!iration or CP immediately.

A,oid mouth to mouth contact.

Administer o$y&en 8ith hi&h concentration.

Call doctor to obtain medical assistance.

3.4.2 E# C-n$'*$ se the a!!ro!riate Personal Protecti,e -ui!ment safely.

"#e$ical safety %o%%les and a full face s#ield attac#ed to a &ide 'ri$$ed

#ard #at &#enever an#ydrous H $ay splas#! <lush immediately 8ith flo8in& 8ater for 2* minutes( by the clock( holdin& the eyelids

o!en. f irritation !ersists( obtain medical ad,ice immediately.

3.4.3 S/n C-n$'*$ se the a!!ro!riate Personal Protecti,e -ui!ment safely.


#ard #at &#enever an#ydrous H $ay splas#! Ru''er loves overalls

'oots are re*uired and sleeve protectors are reco$$ended! A,oid contact 8ith this chemical.

emo,e clothin&( shoes and leather &oods from affected area.

mmediately flush area 8ith runnin& 8ater for at least 2* minutes under runnin& 8ater or other sterile solution.



Co,er affected area 8ith Calcium Dluconate &el or a !aste of )a&nesium +$ide in the

absence of Calcium Dluconate. )assa&in& H< Antidote Del into the 8ound until there is a

cessation of !ain is the most effecti,e first aid treatment a,ailable. H< Antidote Del

contains Calcium Dluconate 8hich combines 8ith H< to form insoluble Calcium <luoride(

thus !re,entin& the e$traction of Calcium from the body tissue and bones.

+btain medical attention AS S++E AS P+SSB9-.

3.4.4 In#$-n se the a!!ro!riate Personal Protecti,e -ui!ment safely.


#ard #at &#enever an#ydrous H $ay splas#! Ru''er loves overalls

'oots are re*uired and sleeve protectors are reco$$ended! Ee,er &i,e anythin& to ,ictim if losin& consciousness or is con,ulsin&.

o not induce ,omitin&.

f ,ictim ,omits naturally( ha,e ,ictim lean for8ard to reduce risk of chokin&.

inse mouth 8ith 8ater.

Ha,e ,ictim drink se,eral *'+*! $'5+#$ 8ith 24*/3** ml of 8ater to dilute material in

stomach.

+btain medical attention.

spo terpapar bahan kimia

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