126484392-kimia-fenilpropanoida

7/23/2019 126484392-KIMIA-FENILPROPANOIDA

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FENIL PROPANOIDA

A. Pe!a"ar

Sen$awa fenil %ro%anoida %ada &m&mn$a 'era(al dari t&m'&han dan )aran*

(e+ali ditem&+an %ada mi+roor*ani(me, Fenil %ro%anoida mewa+ili +elom%o+ 'e(ar

%rod&+ alamiah $an* dit&r&n+an dari a(am aminofenilalanin dan tiro(in ata& dalam

'e'era%a +a(&(- di ten*ah )al&r 'io(inte(i(n$a melal&i 'io(inte(i( a(am (i+imat,

Str&+t&r (ederhana dari fenil %ro%anoida m&lai diteta%+an %ada a+hir a'ad "9

melal&i 'e'era%a ha(il tem&an (en$awa 'ahan alam (e%erti a(am (inamat- a(am

hidro+(i (inamat- a(am 3-.dihidro+(i (inamat- dan meto+(i $an* ditem&+an dalam

+eadaan 'e'a( ma&%&n (e'a*ai e(tern$a,

Fenil %ro%anoida ditem&+an di (el&r&h tanaman- $an* men)adi +om%onen

%entin* dari (e)&mlah (tr&+t&r %olimer- melind&n*i dari (inar &ltra/iolet- mem'eri

%ertahanan terhada%her'i/oradan %ato*en- dan memedia(i intera+(i tanaman

%en$er'&+(e'a*ai %i*men '&n*a dan (en$awa aroma, Kon(entra(i fenil

%ro%anoida dalam tanaman 'er&'ah (e(&ai den*an +eter(ediaan (&m'er da$a,

#. S"ru$"ur %a Ta"a Na&a

Fenil %ro%anoida mer&%a+an t&r&nan dari fenil %ro%ana $an* mem%&n$ai

+eran*+a da(ar +ar'on $an* terdiri dari inin 'en1ena 45 $an* teri+at %ada &)&n*

rantai +ar'on %ro%ana 35, 6erda(ar+an defini(i (en$awa fenil %ro%anoida ter(e'&t-

ma+a di%eroleh *am'aran +eran*+a da(ar fenil %ro%anoida $an* dit&n)&++an %ada

7am'ar ",

7am'ar ", Keran*+a da(ar fenil %ro%ana

8ata nama fenil %ro%anoida tida+ (%e(ifi+ &nt&+ (en$awa t&r&nann$a +arena

%enomoran dari (t&+t&r ini tida+ (elal& dari rantai alifati+n$a $a+ni %ro%ana- teta%i

da%at )&*a 'erda(ar+an +eran*+a +ar'oaromati+n$a, Penomorann$a dim&lai

'erda(ar+an (e(&ai *&*&( f&n*(i $an* men*i+&ti,

6erda(ar+an (tr&+t&rn$a- fenil %ro%anoida di'a*i men)adi
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", 8&r&nan Sinamat

ontoh

Nama I:PA a(am.3.fenil%ro%enoatNama tri/ial a(am (inamat

Nama I:PA a(am 3..hidro+(ifenil5%ro%enoatNama tri/ial a(amp.+&marat

Nama I:PA a(am 3.3-.dihidro+(ifenil5%ro%enoatNama tri/ial a(am +afeat

Nama I:PA a(am 3..hidro+(i.3.meto+(ifenil5%ro%enoatNama tri/ial a(am fer&lat

Nama I:PA a(am 3..hidro+(i.3-#.dimeto+(ifenil5%ro%enoat

Nama tri/ial a(am (ina%at

Nama I:PA etil.3..hidro+(i.3.meto+(ifenil5%ro%enoat

Nama tri/ial etil fer&lat

2, 8&r&nan K&marinontoh


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Nama I:PA 2.+romenonNama tri/ial +&marin

Nama I:PA !.hidro+(i+romen.2.onNama tri/ial &m'eliferon

Nama I:PA 4-!.dhidro+(i.2.+romenon

Nama tri/ial e(+&letin3, 8&r&nan alilfenol

ontoh

Nama I:PA .alilfenol

Nama tri/ial +a/i+ol

Nama I:PA .alil.2.meto+(ifenol

Nama tri/ial e&*enol

Nama I:PA #.alil."-3.'en1odio+(ol

Nama tri/ial (afrol


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Nama I:PA 4.alil..meto+(i."-3.'en1odio+(ol

Nama tri/ial miri(ti(in

, 8&r&nan %ro%enilfenol

ontoh

Nama I:PA 2.meto+(i..".%ro%enil5fenol

Nama tri/ial i(oe&*enol

Nama I:PA ".meto+(i..".%ro%enil5'en1ena

Nama tri/ial anetol

Nama I:PA .meto+(i.4.".%ro%enil5."-3.'en1odio+(ol

Nama tri/ial i(omiri(ti(in

Nama I:PA "-2-3.trimeto+(i.#.".%ro%enil5'en1ena

Nama tri/ial i(oeleme(in

#, Li*nan


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Li*nan 'era(al dari d&a &nit fenil%ro%ana $an* di(at&+an oleh i+atan ;

antara d&a %o(i(i (entral < dan


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6era(al dari t&m'&han en*+eh dan mem%&n$ai aroma $an* men$e*ar+an

dan %eda(, Serta da%at di%eroleh %ada tanaman %ala dan (alam,

I(oe&*enol

6era(al dari t&m'&han +enan*a,

Ka/i+olKa/i+ol adalah airan ta+ 'erwarna $an* ditem&+an 'er(ama.(ama den*an

ter%en dalam min$a+ (irih,

A(am fer&lat

6era(al dari t&m'&han 'era(- *and&m- oat- +o%i- '&ah a%el- nana(- )er&+- dan

+aan* tanah, A(am fer&lat memili+i +elim%ahan dalam dindin* (el tanaman,

Anetol

8erda%at %ada tanaman ada(,

:m'eliferon

:m'eliferon terda%at %ada tanaman famili A%iaeae (e%erti wortel- dan

+et&m'ar,

A(am +afeat

A(am +afeat da%at ditem&+an %ada +&lit Eucalyptus globules- %a+i( air tawar

Salvinia molesta- dan )am&r Phellinus linteus,

A(amp.+&marat

A(amp.+&marat da%at ditem&+an dalam 'er'a*ai tanaman %an*an (e%erti

+aan* tanah- tomat- wortel- 'awan* %&tih, Selain it& ditem&+an )&*a dalam

wine dan &+a,

Miri(ti(in

Miri(ti(in ditem&+an dalam min$a+ at(iri %ala,

Safrol

Safrol ditem&+an dalam min$a+ (a(afra( $an* di%eroleh dari e+(tra+(i +&lit

a+ar ata& '&ah Sasafras albidum,

D. Rea$*i(Rea$*iRea+(i $an* ter)adi %ada fenil %ro%anoida $ait&

", Rea+(i E(terifi+a(iRea+(i e(terifi+a(i adalah rea+(i %er&'ahan dari (&at& a(am

+ar'o+(ilat>t&r&nan +ar'o+(ilat dan al+ohol men)adi (&at& e(ter,


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2, Red&+(i %ada i+atan ran*+a% alifati+ a(am +ar'o+(ilatn$a,

A(am +ar'o+(ilat $an* men*and&n* *&*&( +ar'onil ata& i+atan ran*+a%

+ar'on.+ar'on )i+a direa+(i+an den*an hidro*en di(ertai %em'erian +atali(

a+an men*alami red&+(i (ele+tif- $ait& $an* men*alami red&+(i han$alah

*&*&( +ar'onil dan>ata& i+atan ran*+a% +ar'on.+ar'on (a)a,

3, Red&+(i %ada %o(i(i *&*&( +ar'o+(il den*an red&+tor LiAl?,LiAl?da%at mered&+(i a(am +ar'o+(ilat men)adi al+ohol %rimer,

, Pem'ent&+an halida a(am den*an tionil +lorida SOl25,Pem'ent&+an +lorida a(am adalah den*an merea+(i+an a(am +ar'o+(ilat

dan tionil +lorida SOl25,


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#, Rea+(i.rea+(i %ada +&marin

Keteran*an

"5, Rea+(i red&+(i +&marin den*an men**&na+an LiAl?men*ha(il+an

(&at& al+ohol %rimer,

25, Rea+(i adi(i 'romin men**&na+an %elar&t +ar'on tetra+lorida

35, Rea+(i Diel(.Alder $ait& rea+(i antara (en$awa +ar'onil tida+ )en&h -

den*an (en$awa diena ter+on)&*a(i, Pada rea+(i di ata(- rea+(i Diel(.Alder

ter)adi antara +&marin $an* mer&%a+an (en$awa +ar'onil tida+ )en&h -

den*an 2-3.dimetil."-3.'&tadiena $an* mer&%a+an diena ter+on)&*a(i,

4, Rea+(i hidroli(i(. 6ila eter didih+an dalam air $an* men*and&n* a(am ter)adi hidroli(i(

$an* men*ha(il+an al+ohol,. ?idroli(i( e(ter dalam (&a(ana a(am men*ha(il+an a(am +ar'o+(ilat

dan al+ohol (edan*+an dalam (&a(ana 'a(a men*ha(il+an *aram

+ar'o+(ilat dan al+ohol


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E. Ma+aa" %a P,"e*i

A(am (inamat

Sen$awa ini 'ermanfaat &nt&+ melind&n*i +&lit dari (inar matahari, Sen$awa

ini 'er%oten(i (e'a*ai 'ahan +o(meti+,

K&marin

Sen$awa ini 'ermanfaat (e'a*ai antio+(idan alami- %re+&r(or anti+oa*&lan

warfarin- %enin*+at aroma %i%a tem'a+a& dan min&man 'eral+ohol,Sen$awa ini 'er%oten(i &nt&+ %em'&atan o'at.o'atan (e%erti anti.?I@-

antit&mor- antihi%erten(i- antiimflama(i- anti(e%ti+- anal*e(i+ dan rodenti(ida,

E&*enol

Sen$awa ini 'ermanfaat &nt&+ o'at (a+it *i*i- o'at ain*- dan %enola+

n$am&+, Sen$awa ini di%a+ai dalam ind&(tri %arf&m- %en$eda%- min$a+ at(iri

(erta men)adi +om%onen &tama dalam ro+o+ +rete+, Dalam ind&(tri- e&*enol

da%at di%a+ai &nt&+ mem'&at /anilinSen$awa ini 'er%oten(i &nt&+ anti(e%ti+ dan ane(teti+ 'i&(5,

I(oe&*enol

Sen$awa ini 'ermanfaat &nt&+ 'ahan %em'eri aroma %ada ma+anan /anili5,

A(am Fer&lat

Sen$awa ini 'ermanfaat (e'a*ai antio+(idan alami,

Ka/i+ol

Ka/i+ol di*&na+an (e'a*ai 'ahan dalam %em'&atan %arf&m,

Anetol

Anetol da%at di*&na+an %era(a ma+anan- %re+&r(or (en$awa lain- dan 'i(a

)&*a di*&na+an (e'a*ai anti mi+ro'a- anti )am&r- anti (eran**a,

:m'eliferon

Di*&na+an (e'a*ai %en$era% &ltra/iolet sunscreen).

A(amp.+&marat

A(amp.+&marat memili+i (ifat antio+(idan dan di$a+ini da%at men*&ran*i

ri(i+o +an+er %er&t den*an men*&ran*i %em'ent&+an +ar(ino*eni+

nitro(amina,

F. Ke*i&-u)a", Fenil %ro%anoida mer&%a+an t&r&nan dari fenil %ro%ana $an* mem%&n$ai

+eran*+a da(ar +ar'on $an* terdiri dari inin 'en1ena 45 $an* teri+at%ada &)&n* rantai +ar'on %ro%ana 35,
http://id.wikipedia.org/wiki/Parfumhttp://id.wikipedia.org/w/index.php?title=Penyedap&action=edit&redlink=1http://id.wikipedia.org/wiki/Minyak_atsirihttp://id.wikipedia.org/wiki/Rokok_kretekhttp://id.wikipedia.org/w/index.php?title=Vanilin&action=edit&redlink=1http://id.wikipedia.org/wiki/Parfumhttp://id.wikipedia.org/w/index.php?title=Penyedap&action=edit&redlink=1http://id.wikipedia.org/wiki/Minyak_atsirihttp://id.wikipedia.org/wiki/Rokok_kretekhttp://id.wikipedia.org/w/index.php?title=Vanilin&action=edit&redlink=1


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2, 6erda(ar+an (tr&+t&rn$a- fenil %ro%anoida di'a*i men)adi t&r&nan a(am

t&r&nan (inamat- t&r&nan +&marin- t&r&nan alilfenol- dan t&r&nan

%ro%enilfenol,3, 8ida+ ada tata nama $an* (%e(ifi+ &nt&+ (en$awa t&r&nan fenil %ro%anoida

+arena %enomorann$a tida+ (elal& dari rantai alifati+n$a- $a+ni %ro%ana

teta%i da%at )&*a 'erda(ar+an +eran*+a +ar'oaromati+n$a, Penomorann$a

dim&lai 'erda(ar+an (e(&ai *&*&( f&n*(i $an* men*i+&ti,, Fenil %ro%anoida ditem&+an di (el&r&h tanaman $an* men)adi +om%onen

%entin* dari (e)&mlah (tr&+t&r %olimer- melind&n*i dari (inar &ltra/iolet-

mem'eri %ertahanan terhada% her'i/oradan %ato*en- dan memedia(i

intera+(i tanaman%en$er'&+(e'a*ai %i*men '&n*a dan (en$awa aroma,#, S&m'er (en$awa fenil %ro%anoida di alam &+&% 'era*am- (e%erti en*+eh-

%ala- da&n (alam- +en&r- %adi- *and&m- +o%i- a%el- nana(- )er&+- dll,4, 6an$a+ +em&n*+inan rea+(i $an* ter)adi %ada fenil%ro%anoida- (e%erti

rea+(i e(terifi+a(i- rea+(i red&+(i- rea+(i Diel( Alder- rea+(i hidroli(i( dan

lain.lain, ?al ini +arena *&*&( f&n*(i $an* teri+at %ada fenil%ro%anoida

'ermaam.maam,

Da+"ar Pu*"a$a

", Anonim, 200, Senyawa Aromatik- Online5-

htt%>>+$o(hiro4!,file(,word%re((,om>20"0>0>(en$Baromati+,%%t- dia+(e(2 Can&ari 20"3

2, Anonim, 20"3,Anethole- Online5- htt%>>en,wi+i%edia,or*>wi+i>Anethole- dia+(e(2 Can&ari 20"3,

3, Anonim, 20"3, affeic acid- Online5- htt%>>en,wi+i%edia,or*>wi+i>affeiBaid-dia+(e( 2 Can&ari 20"3,

, Anonim, 20"3, havicol- Online5- htt%>>en,wi+i%edia,or*>wi+i>ha/iol- dia+(e(2 Can&ari 20"3,

#, Anonim, 20"3, oumarin- Online5- htt%>>en,wi+i%edia,or*>wi+i>o&marin-dia+(e( 2 Can&ari 20"3,
http://translate.googleusercontent.com/translate_c?depth=3&ei=NxQBUbPxA8LlrAfMgoGQBQ&hl=id&prev=/search%3Fq%3Dphenylpropanoid%26hl%3Did%26client%3Dfirefox-a%26tbo%3Dd%26rls%3Dorg.mozilla:en-US:official%26biw%3D1252%26bih%3D564&rurl=translate.google.com&sl=en&twu=1&u=http://en.wikipedia.org/wiki/Herbivores&usg=ALkJrhgq_JHLa0x7v8DriX7N0RnJLaltkAhttp://translate.googleusercontent.com/translate_c?depth=3&ei=NxQBUbPxA8LlrAfMgoGQBQ&hl=id&prev=/search%3Fq%3Dphenylpropanoid%26hl%3Did%26client%3Dfirefox-a%26tbo%3Dd%26rls%3Dorg.mozilla:en-US:official%26biw%3D1252%26bih%3D564&rurl=translate.google.com&sl=en&twu=1&u=http://en.wikipedia.org/wiki/Pollinator&usg=ALkJrhi8k-QbZ7YdoXdqlWTNcx8O2eAtUghttp://en.wikipedia.org/wiki/Coumarinhttp://translate.googleusercontent.com/translate_c?depth=3&ei=NxQBUbPxA8LlrAfMgoGQBQ&hl=id&prev=/search%3Fq%3Dphenylpropanoid%26hl%3Did%26client%3Dfirefox-a%26tbo%3Dd%26rls%3Dorg.mozilla:en-US:official%26biw%3D1252%26bih%3D564&rurl=translate.google.com&sl=en&twu=1&u=http://en.wikipedia.org/wiki/Herbivores&usg=ALkJrhgq_JHLa0x7v8DriX7N0RnJLaltkAhttp://translate.googleusercontent.com/translate_c?depth=3&ei=NxQBUbPxA8LlrAfMgoGQBQ&hl=id&prev=/search%3Fq%3Dphenylpropanoid%26hl%3Did%26client%3Dfirefox-a%26tbo%3Dd%26rls%3Dorg.mozilla:en-US:official%26biw%3D1252%26bih%3D564&rurl=translate.google.com&sl=en&twu=1&u=http://en.wikipedia.org/wiki/Pollinator&usg=ALkJrhi8k-QbZ7YdoXdqlWTNcx8O2eAtUghttp://en.wikipedia.org/wiki/Coumarin


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4, Anonim, 20"3, Eugenol- Online5- htt%>>id,wi+i%edia,or*>wi+i>E&*enol- dia+(e(2 Can&ari 20"3,

!, Anonim, 20"3, !soeugenol- Online5-htt%>>en,wi+i%edia,or*>wi+i>I(oe&*enol-dia+(e( 2 Can&ari 20"3,

, Anonim, 20"3, "yristicin- Online5-htt%>>en,wi+i%edia,or*>wi+i>M$ri(tiin-dia+(e( 2 Can&ari 20"3,

9, Anonim, 20"3,p#oumaric acid- Online5- htt%>>en,wi+i%edia,or*>wi+i>%.o&mariBaid- dia+(e( 2 Can&ari 20"3,

"0, Anonim, 20"3, Phenylpropanoid- Online5-htt%>>en,wi+i%edia,or*>wi+i>Phen$l%ro%anoid- dia+(e( 2 Can&ari 20"3,

"", Anonim, 20"3, Safrole- Online5-htt%>>en,wi+i%edia,or*>wi+i>Safrole- dia+(e( 2Can&ari 20"3,

"2, Anonim, 20"3, $mbelliferone- Online5-htt%>>en,wi+i%edia,or*>wi+i>:m'elliferone- dia+(e( 2 Can&ari 20"3,

"3, Dewi+- P, M, 2009, "edicinal %atural Products, :nited Kin*dom Cohn ille$ Son(- Ltd,

", Lenn$- S, 2004, Senyawa &alvonoida' &enil propanoida' dan Alkaloida. Medan:S:- (nline5-repository,&(&,a,id>'it(tream>"23#4!9>"2>">040039,%df5- dia+(e(

2 Can&ari 20"3
http://id.wikipedia.org/wiki/Eugenolhttp://en.wikipedia.org/wiki/Isoeugenolhttp://id.wikipedia.org/wiki/Eugenolhttp://en.wikipedia.org/wiki/Isoeugenol

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