tugas halaman 14
TRANSCRIPT
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8/18/2019 Tugas Halaman 14
1/14
Nama :Ari wieliyani
Kelas :KA14
NIM : 14030234023
1. EDTA
H4Y ↔ H3Y- + H+ Ka1
][
]][[
4
3
Y H
Y H H −+
H3Y- ↔ H2Y
2- + H+ Ka2
][
]][[
3
2
2
−
−+
Y H
Y H H
H2Y2- ↔ HY3- + H+ Ka3
][
]][[2
2
3
−
−+
Y H
HY H
HY3- ↔ Y4- + H+ Ka4
][
]][[
3
4
−
−+
HY
Y H
•
][
][.][
][
][.][
][
][.][
][
][.]H[
3
4
4
2
2
.3
3
3
2
2
2
4
13
+
−−
+
−−
+
−−
+−
=
=
=
=
H
HY K Y
H
Y H K HY
H
Y H K Y H
H
Y H K Y
a
a
a
a
• Ka1 . Ka2 ][
]][[.
][
]][[
3
2
2
4
3
Y H
H Y H
Y H
Y H H +−+
2
421
2
2][
][.][ +
− = H
Y H K K Y H
aa
• Ka2. Ka3
][
]][[.
][
]][[2
2
3
3
2
2
−
+−
−
−+
Y H
H HY
Y H
Y H H
2
3
32
3
][
][.][ +
−− =
H
Y H K K HY
aa
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• Ka3. Ka4
][
]][[.
][
]][[3
4
2
2
3
−
+−
−
−+
HY
H Y
Y H
HY H
2
2
243
4
][
][.][
+
−− =
H
Y H K K Y
aa
• Ka1 . Ka2 . Ka3
][
]][[.
][
]][[.
][
]][[2
2
3
3
2
2
4
3
−
+−+−+
Y H
H HY
Y H
H Y H
Y H
Y H H
3
4321
3
][
][...][ +
− = H
Y H K K K HY
aaa
• Ka1 . Ka2 . Ka3 .Ka4
][
]][[.
][
]][[.
][
]][[.
][
]][[3
4
2
2
3
3
2
2
4
3
−
+−
−
+−
−
+−−+
HY
H Y
Y H
H HY
Y H
H Y H
Y H
Y H H
4
44321
4
][
][...][ +
− = H
Y H K K K K Y
aaaa
• !Y
]][[][][][ 432
234
−−−− +++ Y HY Y H Y H Y H un
++++=
++++=
++++=
+
++++
=++
++++
4
4321321
2
21
3
1
4
4
4
4321
3
321
2
2114
4
44321
3
4321
2
421414
][
][][.][][][
][
...
][
.
][
.
][1][
][
][...
][
].[..
][
].[.
][
][][
H
K K K K H K K K H K K H K H Y H
H
K K K K
H
K K K
H
K K
H
K Y H
H
Y H K Ka Ka Ka
H
Y H Ka Ka Ka
H
Y H Ka Ka
H
Y H KaY H
aaaaaaaaaa
aaaaaaaaaa
a
•
++++=
=
++++
+
4321321
2
21
3
1
4
4
0
][][.][][
][
][
aaaaaaaaaa
Y
K K K K H K K K H K K H K H
H
C
Y H α
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++++=
++++=
++++=
++++=
+
++++−
+++
+−
+
−
+
−
+
−−
+−
−−−−
3
1
4321321
2
21
3
1
4
3
3
432
2
322
3
3
3
4323
2
32323
3
1
3
432
234
][
][][][][][
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..
][
.
][1
][
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.][
][
][][
]][[
][][][][][
H K
K K K K H K K K H K K H K H Y H
H
K K K
H
K K
H
K
K
H
Y H
H
K K K Y H
H
K K Y H
H
K Y H Y H
K
H Y H
Y HY Y H Y H Y H C
a
aaaaaaaaaa
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a
aaaaaa
a
Y
•
++++=
=
++++
+
−
4321321
2
21
3
1
4
3
1
3
1
][][.][][
][
][
aaaaaaaaaa
a
Y
K K K K H K K K H K K H K H
H K
C
Y H α
++++=
++++=
++++=
++++=
+
++++−
++
++−
+
−
+
−−
+−+−
−−−−
3
21
4321321
2
21
3
1
4
2
2
2
433
221
22
2
2
43
2
23
2
22
2
2
2
2
21
22
2
432
234
][.
][][][][][
][
.
][1
][
.
][][
][
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]][[]][[
][][][][][
H K K
K K K K H K K K H K K H K H Y H
H
K K
H
K
K
H
K K
H Y H
H
K K Y H
H
K Y H Y H
K
H Y H
K K
H Y H
Y HY Y H Y H Y H C
aa
aaaaaaaaaa
aaa
aaa
aaa
aaa
Y
•
++++=
=
++++
+
−
4321321
2
21
3
1
4
2
21
2
2
2
][][.][][
][.
][
aaaaaaaaaa
aa
Y
K K K K H K K K H K K H K H
H K K
C
Y H α
++++=
+++++=
++++=
++++=
+
++++−
+
+++−
+
−−
+−+−+−
−−−−
][..
][][][][][
][1
][1
][
..
][][
][
][
][
]][[
.
]][[
.
]][[
][][][][][
321
4321321
2
21
3
1
4
3
4
332
2
321
3
3
43
33
3
32
2
3
321
3
3
432
234
H K K K
K K K K H K K K H K K H K H Y H
H
K
K
H
K K
H
K K K
H Y H
H
K Y H Y H
K
H Y H
K K
H Y H
K K K
H Y H
Y HY Y H Y H Y H C
aaa
aaaaaaaaaa
a
aaaaaa
a
aaaaaa
Y
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•
++++=
=
++++
+
−
4321321
2
21
3
1
4
321
3
3
][][.][][
][..
][
aaaaaaaaaa
aaa
Y
K K K K H K K K H K K H K H
H K K K
C
Y H α
++++=
++++=
++++=
++++=
++++−
++++−
−+−+−+−+−
−−−−
4321
4321321
2
21
3
1
4
4
443
2
432
3
4321
44
4
4
4
43
24
432
34
4321
44
432
234
...
][][][][][
1][
.
][
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][
..
][][
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.
]][[
..
]][[
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]][[
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aaaa
aaaaaaaaaa
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Y
K K K K
K K K K H K K K H K K H K H Y
K
H
K K
H
K K K
H
K K K K
H Y
Y K
H Y
K K
H Y
K K K
H Y
K K K K
H Y
Y HY Y H Y H Y H C
A"a#$n %H+& "a#a' "i(a)ar*an "ari *ese'im)anan m$a'an
][][4][3][2][][ 432
23
−−−−−+ ++++= OH Y HY Y H Y H H
+
+++++
++++
+
++++
+
++++
=
+++++
++++
+
++++
+
++++
+
][][][][][.....4
][][][][
][....3
][][][][
][...2
][][][][
][.
4321321
2
21
3
1
4
4321
4321321
2
21
3
1
4
321
4321321
2
21
3
1
4
2
21
4321321
2
21
3
1
4
3
1
H
K
K K K K H K K K H K K H K H
K K K K C
K K K K H K K K H K K H K H
H K K K C
K K K K H K K K H K K H K H
H K K C
K K K K H K K K H K K H K H
H K C
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aaaaaaaaaa
aaaaY
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aaaY
aaaaaaaaaa
aaY
aaaaaaaaaa
aY
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++++
+++++
++++
++
++++
++
++++
++
++++
=
+++++
++++
+++++
+
+++++
+
+++++
+
+++++
++
][][][][][
][][][][
][][][][][
][...4
][][][][][
][...3
][][][][][
][..2
][][][][][
][.][
4321
2
321
3
21
4
1
5
4321321
2
21
3
1
4
4321
2
321
3
21
4
1
5
4321
4321
2
321
3
21
4
1
5
2
321
4321
2
321
3
21
4
1
5
3
21
4321
2
321
3
21
4
1
5
4
1
H K K K K H K K K H K K H K H
K K K K K H K K K K H K K K H K K H K
H K K K K H K K K H K K H K H
H K K K K C
H K K K K H K K K H K K H K H
H K K K C
H K K K K H K K K H K K H K H
H K K C
H K K K K H K K K H K K H K H
H K C H
aaaaaaaaaa
aaaaW aaaW aaW aW W
aaaaaaaaaa
aaaaY
aaaaaaaaaa
aaaY
aaaaaaaaaa
aaY
aaaaaaaaaa
aY
0][][][][
][.][..4
][..3][.2][][][][
321
2
21
3
1
4
4
1
4
431
4
21
3
1
2
321
3
21
5
1
6
=++++
+
++++++
++++
++
++++++
H K K K K H K K K H K K H K
H K C H K K K C
H K K C H K C H K K K H K K H K H
aaaW aaW aW W
aY aaaY
aaY aY aaaaaa
• A#a)ila s$m)anan %H+& "ari "issiasi *e 2/3 "ia)ai*an / ma*a #ers. le)i
se"erana lai
! A
][][][ 2
234
−− ++ Y H Y H Y H un
++
=
++=
++=
++=
++
+
+
++
+
++
211
2
2
4
2
211
2
4
2
211
4
2
42141
4
.][][
][][
][
.][][][
][
.
][1][
][
].[.
][
][][
aaa
A
aaa
aaa
K K H K H
H C Y H
H
K K H K H Y H
H
K K
H
K Y H
H
Y H Ka Ka
H
Y H KaY H
• A#a)ila s$m)anan %H+& "ari "issiasi *e 2/3/4 "ia)ai*an ma*a #ers. le)i
se"erana lai
! A
][][ 34−+ Y H Y H
un
-
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+
=
+=
+=
+=
+
+
+
+
+
+
1
24
14
14
414
][
][][
][
][][
][1][
][
][][
a
A
a
a
K H
H C Y H
H
K H Y H
H
K Y H
H
Y H KaY H
• Dari *ese'im)anan m$a'an
][][4][3][2][][ 43223
−−−−−+ ++++= OH Y HY Y H Y H H "enan mena)ai*an
][][],[],[ 4322−−−−
OH danY HY Y H
men(a"i %H+& "an %H3Y-&
%H+&
][ 3−
Y H
0][][
][
][][
][
][
][][
][
][
11
1
1
1
41
=−+
+
=
+
=
=
++
+
++
+
+
+
+
+
Aaa
a
A
a
A
a
C K K H H
K H
H C H
K H
H C
H
K H
H
Y H Ka
• ena)aian le)i lan($'
][][1
++ =+ H K H a
ai A
a A
a
A
a
A
K C H
K C H
H
K C H
K H
H C H
.][
.][
][][
][
][][
1
1
1
=
=
=
+
=
+
+
++
+
++
-
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1. H34
3 4 2 4 H PO H PO H
− ++ ƒ Ka1
][
]][[
43
42
PO H
PO H H −+
H24- H4
2- + H+ Ka2
][
]][[
42
2
4
−
−+
PO H
HPO H
H42- 4
3- + H+ Ka3
][
]][[2
4
3
4
−
−+
HPO
PO H
•
1
4243
]][[][
Ka
PO H H PO H
−+
=
•
2
442
]][[][
Ka
HPO H PO H
−+
=
•
3
3
42
4
]][[
][ Ka
PO H
HPO
−+−
=
Ka1 . Ka2 . Ka3
][
]][[
43
42
PO H
PO H H −+
.
][
]][[
42
2
4
−
−+
PO H
HPO H
.
][
]][[2
4
3
4
−
−+
HPO
PO H
Ka1 . Ka2 . Ka3
3
433213
4
43
3
4
3
][
].[..][
][
][][+
−−+
=→ H
PO H Ka Ka Ka PO
PO H
PO H
Ka1 . Ka2
][
]][[
43
42
PO H
PO H H −+
.
][
]][[
42
2
4
−
−+
PO H
HPO H
][
][][
43
2
4
2
PO H
HPO H −+
Ka2 . Ka3
][
]][[
42
2
4
−
−+
PO H
HPO H
.
][
]][[2
4
3
4
−
−+
HPO
PO H
][
][][
42
3
4
2
−
−+
PO H
PO H
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! A
][][][][ 3
4
2
44243
−−− +++ PO HPO PO H PO H un
! A
3
43321
2
432143143
][
].[..
][
].[.
][
][][ +++ +++
H
PO H Ka Ka Ka
H
PO H Ka Ka
H
PO H Ka PO H
un
Ka2 . Ka3
][
][][
42
3
4
2
−
−+
PO H
PO H
! A
+++ +++ 3
321
2
21143
][
..
][
.
][1][
H
Ka Ka Ka
H
Ka Ka
H
Ka PO H
+++= +
+++
3
32121
2
1
3
43
A
][
..].[.].[][
][
C
H
Ka Ka Ka H Ka Ka H Ka H
PO H
•
+++
== ++++
32121
2
1
3
3
430
..].[.].[][
][][
Ka Ka Ka H Ka Ka H Ka H
H
C
PO H
A
α
][........... 421−→= PO H α
! A
2
324224242
1
42
][
.].[
][
].[][
]][[+
−
+
−−
−+
+++ H
Ka Ka PO H
H
Ka PO H PO H
Ka
PO H H
! A
+++ ++
+−
2
322
1
42][
.
][1
][][
H
Ka Ka
H
Ka
Ka
H PO H
3
1
321
2
21
3
1
4
42
A
].[
].[..].[.].[][
][
C+
++++
−
+++=
H Ka
H Ka Ka Ka H Ka Ka H Ka H
PO H
•
3
2 4 11 4 3 2
1 1 2 1 2 3
[ ] .[ ]
[ ] .[ ] . .[ ] . . .[ ] A
H PO Ka H
C H Ka H Ka Ka H Ka Ka Ka H α
+
+ + + +
= = ÷+ + +
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2 4..............? [ ] HPOα
−= →
! A
2 3
3 4 2 4 4 4[ ] [ ] [ ] [ ]
un H PO H PO HPO PO
− − −+ + +
! A
22 2 22 3 44 44
1 2 2
[ ][ ] [ ] [ ][ ][ ]
. [ ]
Ka HPO H HPO H HPO HPO
Ka Ka Ka H
−+ − + −−
++ + +
! A
22 34
1 2 2
[ ] [ ][ ] 1
. [ ]
Ka H H HPO
Ka Ka Ka H
+ +−
+
+ + + ÷
3 2
1 1 2 1 2 3
2
4 1 2
[ ] .[ ] . .[ ] . .
[ ] . .[ ]
A H Ka H Ka Ka H Ka Ka Ka
HPO Ka Ka H
C + + +
− +
+ + += ÷
•
2
4 1 22 3 2
1 1 2 1 2 3
[ ] . .[ ]
[ ] .[ ] . .[ ] . . A
HPO Ka Ka H
H Ka H Ka Ka H Ka K K C a aα
− +
+ + += = + + +
3
3 4........? [ ] POα
−
= →
! A
2 3
3 4 2 4 4 4[ ] [ ] [ ] [ ]un H PO H PO HPO PO− − −+ + +
! A
3 3 2 3 334 4 44
1 2 3 2 3 3
[ ] [ ] [ ] [ ] [ ][ ][ ]
. . .
H PO H PO H PO PO
Ka Ka Ka Ka Ka Ka
+ − + − + −−+ + +
! A
3 23
4
1 2 3 2 3 3
[ ] [ ] [ ][ ] 1
. . .
H H H PO
Ka Ka Ka Ka Ka Ka
+ + +− + + + ÷
3 2
1 1 2 1 2 3
3
4 1 2 3
[ ] .[ ] . .[ ] . .
[ ] . .
A H Ka H Ka Ka H Ka Ka KaC
PO Ka Ka Ka
+ + +
−
+ + += ÷
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3
1 2 34
3 2
1 1 2 1 2 3
. .[ ]
[ ] .[ ] . .[ ] . . A
Ka Ka Ka PO
C H Ka H Ka Ka H Ka Ka Ka
−
+ + +
= ÷+ + +
A"a#$n %H+& "a#a' "i(a)ar*an "ari *ese'im)anan m$a'an
%H+& %H24-& + 2%H4
2-& + 3%43-& + %H-&
3
1
4 3 2
1 1 2 1 2 3
. .[ ][ ]
[ ] .[ ] . .[ ] . . .[ ]
AC Ka H
H H Ka H Ka Ka H Ka Ka Ka H
++
+ + + +
= ÷+ + +
+
1 2
3 2
1 1 2 1 2 3
2 . . .[ ][ ] .[ ] . .[ ] . .
AC Ka Ka H H Ka H Ka Ka H Ka Ka Ka
+
+ + + ÷+ + + +
1 2 3
3 2
1 1 2 1 2 3
3 . . .
[ ] .[ ] . .[ ] . . [ ]
AC Ka Ka Ka Kw
H Ka H Ka Ka H Ka Ka Ka H + + + +
+ ÷+ + +
3
1
4 3 2
1 1 2 1 2 3
. .[ ][ ]
[ ] .[ ] . .[ ] . . .[ ]
AC Ka H
H
H Ka H Ka Ka H Ka Ka Ka H
++
+ + + +
= ÷
+ + + +
2
1 2
4 3 2
1 1 2 1 2 3
2 . . .[ ]
[ ] .[ ] . .[ ] . . .[ ]
AC Ka Ka H
H Ka H Ka Ka H Ka Ka Ka H
+
+ + + +
÷+ + +
+
1 2 3
4 3 2
1 1 2 1 2 3
3 . . . .[ ]
[ ] .[ ] . .[ ] . . .[ ]
AC Ka Ka Ka H
H Ka H Ka Ka H Ka Ka Ka H
+
+ + + +
÷+ + +
+
( )3 21 1 2 1 2 34 3 2
1 1 2 1 2 3
[ ] .[ ] . .[ ] . .
[ ] .[ ] . .[ ] . . .[ ]
Kw H Ka H Ka Ka H Ka Ka Ka
H Ka H Ka Ka H Ka Ka Ka H
+ + +
+ + + +
+ + + ÷ ÷+ + +
•
5 4 3 2
1 1 2 1 2 3[ ] .[ ] . .[ ] . . .[ ] H Ka H Ka Ka H Ka Ka Ka H
+ + + ++ + + =
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3 2 3 2
1 1 2 1 2 3 1
1 2 1 2 3
. .[ ] 2 . . .[ ] 3 . . . .[ ] .[ ] . .[ ]
. . .[ ] . . . .
A A AC Ka H C Ka Ka H C Ka Ka Ka H Kw H Kw Ka H
Kw Ka Ka H Kw Ka Ka Ka
+ + + + +
+
+ + + +
+ +
•
5 4 3 3 2
1 1 2 1 2 3
2 2 31 2 1 1 1 2 3
1 2 1 2 3
[ ] .[ ] . .[ ] .[ ] . . .[ ]
2 . . .[ ] . .[ ] . .[ ] 3 . . . .[ ]
. . .[ ] . . . 0
A A A
H Ka H Ka Ka H Kw H Ka Ka Ka H
C Ka Ka H Kw Ka H C Ka H C Ka Ka Ka H
Kw Ka Ka H Kw Ka Ka Ka
+ + + + +
+ + + +
+
+ + − + −
− − − −− =
•
( ) ( )
( )
5 4 3 2
1 1 2 1 1 2 3 1 2 1
1 2 3 1 2 1 2 3
[ ] .[ ] . . [ ] . . 2. . . . [ ]
3 . . . . [ ] . . 0
H Ka H Ka Ka Ca Ka Kw H Ka Ka Ka Ca Ka Ka Kw Ka H
CaKa Ka Ka Kw Ka Ka H Kw Ka Ka Ka
+ + + +
+
+ + − − + − −
− + − =
,ila s$m)anan %H-& Kw "ari #enam)aan *nsen'rasi %H+& "alam lar$'an %H+&
"ia)ai*an/ ma*a
%H+&
3 2
1 1 .2 1 .2 3
4 3 2
1 1 .2 1 .2 3
. .[ ] 2 . . .[ ] 3 . . . .[ ]
[ ] .[ ] . .[ ] . . .[ ]
A A AC Ka H C Ka Ka H C Ka Ka Ka H
H Ka H Ka Ka H Ka Ka Ka H
+ + +
+ + + +
+ ++ + +
5 4 3 3 2 2
1 1 .2 1 1 .2 .3 1 .2
1 .2 3
[ ] .[ ] . .[ ] . .[ ] . . [ ] 2 . . .[ ]
3 . . . [ ] 0
H Ka H Ka Ka H Ca Ka H Ka Ka Ka H Ca Ka Ka H
Ca Ka Ka Ka H
+ + + + + +
++ + + + −− =
:[ ] H +
( ) ( )4 3 21 1 2 1 1 2 3 1 2
1 2 3
[ ] .[ ] . . [ ] . . 2 . . [ ]
3 . . . 0
H Ka H Ka Ka Ca Ka H Ka Ka Ka Ca Ka Ka H
Ca Ka K a Ka
+ + + ++ + − + −
− =
A#a)ila s$m)anan %H+& "ari "issiasi *e'ia "ia)ai*an ma*a le)i se"erana lai
2
3 4 2 4 4[ ] [ ] [ ]
AC H PO H PO HPO
− −= + +
1 3 4 1 .2 3 43 4 2
.[ ] . .[ ][ ]
[ ] [ ] A
Ka H PO Ka Ka H POC H PO
H H + += + +
-
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1 .213 4 2
.[ ] 1
[ ] [ ] A
Ka Ka KaC H PO
H H + +
= + + ÷
2
1 1 .23 4 2
[ ] .[ ] .[ ][ ]
A H Ka H Ka KaC H PO H
+ +
+ + += ÷
2
3 4 2
1 1 .2
[ ][ ]
[ ] .[ ] . A
H H PO C
H Ka H Ka Ka
+
+ +
= ÷+ +
3 4 2 4[ ] [ ]
AC H PO H PO
−= +
1 2 43 4
.[ ][ ]
[ ] A
Ka H POC H PO
H += +
13 4[ ] 1
[ ] A
KaC H PO
H +
= + ÷
13 4 [ ][ ]
[ ] A
H KaC H PO
H
+
+ += ÷
3 4
1
[ ][ ]
[ ] A
H H PO C
H Ka
+
+
= ÷+
2 4[ ] [ ] H H PO
+ =
1 3 4.[ ][ ][ ]
Ka H PO H
H
++=
1
1
[ ][ ]
[ ] [ ] A
Ka H H C
H H Ka
++
+ +
= ÷ ÷ +
-
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