kinetik tugas
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kinetikaTRANSCRIPT
Waktu(jam) ln [A] Orde 1 Sisa dalam tanah (mg/kg)30 1.60983783245543 5.00260 1.48432810139126 4.41290 0.832909122935104 2.3
120 0.625938430866495 1.87240 -1.06421086195078 0.345480 -1.83258146374831 0.16
3000 -36.2760476788547 1.76E-163600 -43.9306386435103 8.34E-204800 -56.9333555480093 1.88E-256000 -74.5454729407556 4.22E-33
orde reaksi 1: k= 0,012
Waktu(jam) 1/[A] Orde 1 Sisa dalam tanah (mg/kg)30 0.199920031987205 5.00260 0.226654578422484 4.41290 0.434782608695652 2.3
120 0.53475935828877 1.87240 2.89855072463768 0.345480 6.25 0.16
3000 5681818181818182 1.76E-163600 1.19904076738609E+019 8.34E-204800 5.31914893617021E+024 1.88E-256000 2.3696682464455E+032 4.22E-33
Waktu(jam)30 0.0399680191897651 25.02000460 0.051372297919874 19.46574490 0.189035916824197 5.290000
120 0.285967571277417 3.496900240 8.40159630329763 0.119025480 39.0625 0.025600
3000 3.22830578512397E+031 0.0000003600 1.43769876185383E+038 0.0000004800 2.82933454051607E+049 0.0000006000 5.61532759821208E+064 0.000000
1. Reaksi peruraian pestisida fosfonium di dalam sistem tanah oleh penambahan oksidan diamati dengan mengukur sisa pestisida pada variasi waktu reaksi:
1/[A]² [A]²
2. Hidrolisis suatu gula oleh asam lemah memberikan data perubahan konsentras iversus waktu sebagai berikut:
waktu ln [M] Kons.(M)0 0 11 -0.232999461625138 0.7921542 -0.466000452659933 0.6275073 -0.699000276555214 0.4970824 -0.932000994329804 0.3937655 -1.16499891650332 0.3119236 -1.3979985891519 0.2470917 -1.63099868436119 0.1957348 -1.86400118392407 0.1550519 -2.09700284262554 0.122824
10 -2.32999740060438 0.097296
orde reaksi 1: k= 0,233
waktu 1/[M] Kons.(M)0 1 11 1.26238079969299 0.7921542 1.59360772071069 0.6275073 2.01174051766107 0.4970824 2.53958579355707 0.3937655 3.20591940959788 0.3119236 4.04709196207065 0.2470917 5.10897442447403 0.1957348 6.44949081270034 0.1550519 8.14173125773464 0.122824
10 10.277914816642 0.097296
waktu0 1 11 1.59360528343351 0.6275079597162 2.53958556750871 0.3937650350493 4.04709991039923 0.2470905147244 6.4494960028369 0.1550508752255 10.2779192608364 0.0972959579296 16.3789533494569 0.0610539622817 26.1016196699298 0.0383117987568 41.5959317431061 0.0240408126019 66.2877878731734 0.015085734976
10 105.635532978149 0.009466511616
1/[M]² [M]²
orde reaksi 1: k= 0,233time(menit) ln [C] conc.
0 0.916290731874155 2.520 0.0676586484738149 1.0740 -0.385662480811985 0.6860 -0.693147180559945 0.580 -0.941608539858445 0.39
100 -1.13943428318836 0.32120 -1.27296567581289 0.28140 -1.42711635564015 0.24160 -1.56064774826467 0.21180 -1.66073120682165 0.19200 -1.77195684193188 0.17
time(menit) 1/[C] conc.0 0.4 2.5
20 0.934579439252336 1.0740 1.47058823529412 0.6860 2 0.580 2.56410256410256 0.39
100 3.125 0.32120 3.57142857142857 0.28140 4.16666666666667 0.24160 4.76190476190476 0.21180 5.26315789473684 0.19200 5.88235294117647 0.17
time(menit)0 0.16 6.25
20 0.873438728273212 1.144940 2.16262975778547 0.462460 #VALUE! s80 6.57462195923734 0.1521
100 9.765625 0.1024120 12.7551020408163 0.0784140 17.3611111111111 0.0576160 22.6757369614513 0.0441180 27.7008310249307 0.0361200 34.6020761245675 0.0289
1/[C]² [C]²
Sisa dalam tanah (mg/kg)5.0024.412
2.31.87
0.3450.16
1.76E-168.34E-201.88E-254.22E-33
1. Reaksi peruraian pestisida fosfonium di dalam sistem tanah oleh penambahan oksidan diamati dengan mengukur sisa pestisida
0 1000 2000 3000 4000 5000 6000 7000
-80
-70
-60
-50
-40
-30
-20
-10
0
10
f(x) = − 0.0126939005630015 x + 2.37923547213077R² = 0.998955610712577
ln [A] Orde 1
ln [A] Orde 1Linear (ln [A] Orde 1)
0 1000 2000 3000 4000 5000 6000 70000
5E+031
1E+032
1.5E+032
2E+032
2.5E+032
f(x) = 2.07935124394138E+028 x − 1.46049669170292E+031R² = 0.405398644419672
1/[A] Orde 1
1/[A] Orde 1Linear (1/[A] Orde 1)
0 1000 2000 3000 4000 5000 6000 70000
1E+064
2E+064
3E+064
4E+064
5E+064
6E+064
f(x) = 4.92737253729123E+060 x − 3.46089261547836E+063R² = 0.405398629450109
1/[A]²
1/[A]² Linear (1/[A]² )
2. Hidrolisis suatu gula oleh asam lemah memberikan data perubahan konsentras iversus waktu sebagai berikut:
Kons.(M)1
0.7921540.6275070.4970820.3937650.3119230.2470910.1957340.1550510.1228240.097296
0 2 4 6 8 10 12
-2.5
-2
-1.5
-1
-0.5
0f(x) = − 0.232999973920454 x − 2.15195905539645E-08R² = 0.999999999996234
ln [M]
ln [M]Linear (ln [M])
0 2 4 6 8 10 120
2
4
6
8
10
12
f(x) = 0.874332719758955 x − 0.222714733809198R² = 0.908534923000796
1/[M]
1/[M]Linear (1/[M])
0 2 4 6 8 10 120
20
40
60
80
100
120
f(x) = 8.66510846038344 x − 17.6975848802054R² = 0.738646110212036
1/[M]²
1/[M]²Linear (1/[M]²)
conc.2.5
1.070.680.5
0.390.320.280.240.210.190.17
0 50 100 150 200 250
-2
-1.5
-1
-0.5
0
0.5
1
1.5
f(x) = − 0.0116722948084931 x + 0.27001848698186R² = 0.882345864025354
ln [C]
ln [C]Linear (ln [C])
0 50 100 150 200 2500
1
2
3
4
5
6
7
f(x) = 0.0272457670219598 x + 0.379039759127864R² = 0.999639287114744
1/[C]
1/[C]Linear (1/[C])
0 50 100 150 200 2500
5
10
15
20
25
30
35
40
f(x) = 0.168104043173594 x − 4.01970321923653R² = 0.936619663557679
1/[C]²
1/[C]²Linear (1/[C]²)
0 1000 2000 3000 4000 5000 6000 7000
-80
-70
-60
-50
-40
-30
-20
-10
0
10
f(x) = − 0.0126939005630015 x + 2.37923547213077R² = 0.998955610712577
ln [A] Orde 1
ln [A] Orde 1Linear (ln [A] Orde 1)
0 1000 2000 3000 4000 5000 6000 70000
5E+031
1E+032
1.5E+032
2E+032
2.5E+032
f(x) = 2.07935124394138E+028 x − 1.46049669170292E+031R² = 0.405398644419672
1/[A] Orde 1
1/[A] Orde 1Linear (1/[A] Orde 1)
0 1000 2000 3000 4000 5000 6000 70000
1E+064
2E+064
3E+064
4E+064
5E+064
6E+064
f(x) = 4.92737253729123E+060 x − 3.46089261547836E+063R² = 0.405398629450109
1/[A]²
1/[A]² Linear (1/[A]² )
0 2 4 6 8 10 12
-2.5
-2
-1.5
-1
-0.5
0f(x) = − 0.232999973920454 x − 2.15195905539645E-08R² = 0.999999999996234
ln [M]
ln [M]Linear (ln [M])
0 2 4 6 8 10 120
2
4
6
8
10
12
f(x) = 0.874332719758955 x − 0.222714733809198R² = 0.908534923000796
1/[M]
1/[M]Linear (1/[M])
0 2 4 6 8 10 120
20
40
60
80
100
120
f(x) = 8.66510846038344 x − 17.6975848802054R² = 0.738646110212036
1/[M]²
1/[M]²Linear (1/[M]²)
0 50 100 150 200 250
-2
-1.5
-1
-0.5
0
0.5
1
1.5
f(x) = − 0.0116722948084931 x + 0.27001848698186R² = 0.882345864025354
ln [C]
ln [C]Linear (ln [C])
0 50 100 150 200 2500
1
2
3
4
5
6
7
f(x) = 0.0272457670219598 x + 0.379039759127864R² = 0.999639287114744
1/[C]
1/[C]Linear (1/[C])
0 50 100 150 200 2500
5
10
15
20
25
30
35
40
f(x) = 0.168104043173594 x − 4.01970321923653R² = 0.936619663557679
1/[C]²
1/[C]²Linear (1/[C]²)