KONSTANTA1. Inisiasi 2. PropagasiHubungan kd dan suhu (Brandrup, 1975 ) Ep/R 3.9103E+03 (Buback, 1995)

T, C 1/T, K kd, s-1 Ap 4.2658E+0734.8 0.0032473 3.89E-08 kp dalam (L/mol/s)49.4 0.0031003 5.28E-0761 0.0029927 2.58E-06

74.8 0.002874 1.83E-05100 0.0026799 4.58E-04

3. TerminasiEt 14200.00 (Brandrup, 1975)At 2.55E+04

maka, Ad 5.5258E+15 s-1 R 8.31Ed/R 1.6397E+04 K kt dalam (L/mol/s)y kdx 1/T

0.8 (Flory, 1953)1350

1405890.906

0.034799309 mol/L8.699827156 mol/L

t1 477.5 s= 0.13 jam[M] 0.08864 mol/L[I] 3.47E-02 mol/LT 90 oC= 363.15 KKonversi 98.98 %

Menghitung konstanta pada suhu 90 Ckd 1.36E-04 s-1

kp 898.81299 L/mol/skt 231.19 L/mol/s

Rho 8.0667981 mol/L= 840.076359 g/L RHO=c1/(c2**(1+(1-(T/c3))**c4))BM 104.14 c1 0.7397

c2 0.2603r0 0.005 dm c3 636r1 0.01 dm c4 0.3009

t2 1649.0398 s= 0.46 jam

t, s r1, dm V, L Fs0, mol/s Fi0, mol/s Fs0, kg/jam Fi0, kg/jam0 0.00500 5.23599E-07 5.33E-09 2.47E-12 2.00E-06 2.15E-09

200 0.00544 6.73795E-07 6.85E-09 3.17E-12 2.57E-06 2.77E-09400 0.00592 8.67076E-07 8.82E-09 4.08E-12 3.31E-06 3.56E-09600 0.00643 1.1158E-06 1.14E-08 5.26E-12 4.26E-06 4.58E-09800 0.00700 1.43587E-06 1.46E-08 6.76E-12 5.48E-06 5.90E-09

1000 0.00761 1.84776E-06 1.88E-08 8.70E-12 7.05E-06 7.59E-091200 0.00828 2.37779E-06 2.42E-08 1.12E-11 9.07E-06 9.77E-091400 0.00901 3.05987E-06 3.11E-08 1.44E-11 1.17E-05 1.26E-081600 0.00980 3.93761E-06 4.01E-08 1.86E-11 1.50E-05 1.62E-08

1649.04 0.01000 4.18879E-06 4.26E-08 1.97E-11 1.60E-05 1.72E-08

TAHAP 2

HASIL PROGRAM -CHECK FORTRAN-

[Io]

TAHAP 1

fXnMrSpec gravity stiren

[Mo]

y = 5.5258E+15e-1.6397E+04x1.00E-08

1.00E-07

1.00E-06

1.00E-05

1.00E-04

1.00E-03

1.00E-02

1.00E-01

1.00E+000.0025 0.0026 0.0027 0.0028 0.0029 0.003 0.0031 0.0032 0.0033