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Resume: Counter Electrodes Material berbasis Graphene Risa Rahmawati Sunarya 27 November 2015

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Page 1: counter elektroda

Resume: Counter Electrodes Material berbasis Graphene

Risa Rahmawati Sunarya27 November 2015

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Latar Belakang

• Pt masih merupakan CE terbaik sampai saat ini• Hanya Pt, logam mulia, harganya mahal• Perlu pengembangan CE lain yang low-cost

material, tetapi well-performed

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Beberapa material berbasis karbon yang sudah dikembangkan

• Graphene Supported Platinum Nanoparticle, Ƞ=2,91%, Pt=2,11% (Bajpai, R.; Roy, S.; Kumar, P.; Bajpai, P. :2011)

• Multi-Wall Carbon Nanotube Hybrid, Ƞ=7,36%, Pt=7,54% (W, J.; Yue, G.; Xiao, Y.; Huang, M.; 2012)

• Graphene Quantum-Dot-Doped Polypyrrole, Ƞ=5,27%, Pt=6,2% (Chen, L.; Guo, C.X.; Zhang, Q.; Lei, Y. :2013)

• Reduced Graphene Oxide−TaON Composite , Ƞ=7,65%, Pt=7,91% (Li, Y.; Wang, H.; Feng, Q.; Zhou, G. : 2013)

• Nitrogen-Doped TiO2/Graphene Nanohybrids , Ƞ=5,04, Pt=6,4% (Wang, R.; Wu, Q.; Lu, Y.; Liu, H.; Xia, Y.; Liu, J.; Yang, D. :2012)

• Catalytic Multiwall Carbon Nanotube , Ƞ= 7,67%, Pt=8,03% (Lee, J.W.; Ramasamy, E.; Lee, D.Y.; Song, J.S.: 2009)

• Vertically Aligned Single-Walled Carbon Nanotubes, , Pt=5,6% (Dong, P.; Pint, C.L.; Hainey, M.; 2011)

• Sub-micrometer-sized Graphite, Ƞ= 6,2 %, Pt=5,6% (Veerappan, G; Bojan, K.; Rhee, S.W.; 2011)

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SEM Images Graphene

(a) G-Pt (b) QDP-doped (c) RGO-TaON

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TEM Images

(a) G-Pt (b) QDP-doped (c) RGO-TaON (d) NTA-G700

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a ba

Cc

C d

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Kesimpulan: Photovoltaic PerformanceCE Voc(mV) Jsc(mA.cm-2 FF Ƞ (%)

Std Pt 0,68 5,05 0,58 2,00

G-Pt2 0,74 6,67 0,59 2,91

Std Pt 0,696 67,5 6,20

GQD 0,723 50,8 5,27

Std Pt 0,835 13,73 0,69 7,91

RGO-TaON 0,829 13,38 0,69 7,65

Std Pt 0,78 12,62 0,64 6,40

N-TA-G700 0,72 13,73 0,51 5,04

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Reference • Bajpai, R.; Roy, S.; Kumar, P.; Bajpai, P., J.ACS.Applied Materials and Inter, 2011,

2119-2124• W, J.; Yue, G.; Xiao, Y.; Huang, M., J.ACS.Applied Materials and Inter, 2012• Chen, L.; Guo, C.X.; Zhang, Q.; Lei, Y., J.ACS.Applied Materials and Inter 2013• Li, Y.; Wang, H.; Feng, Q.; Zhou, G., J.ACS.Applied Materials and Inter, 2013, 8217-

8224• Wang, R.; Wu, Q.; Lu, Y.; Liu, H.; Xia, Y.; Liu, J.; Yang, D., J.ACS.Applied Materials and

Inter 2012• Lee, J.W.; Ramasamy, E.; Lee, D.Y.; Song, J.S., J.ACS.Applied Materials and Inter 2009• Dong, P.; Pint, C.L.; Hainey, M., J.ACS.Applied Materials and Inter, 2011, 3157-3161• Veerappan, G; Bojan, K.; Rhee, S.W., J.ACS.Applied Materials and Inter 2011• S. Shalini a, R.Balasundaraprabhu a,n, S.Prasanna a, TapasK.Mallick b,

S.Senthilarasu., J. Renewable and Sustainable Energy, 2015, 1306-1325